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J.Health Sci., 50(1), 9-16, 2004

Dioxin Concentration of Particulate and Gaseous Substances in the Ambient Air by Particle Size - Comparison between Specimens Collected in Summer and in Winter at Tokyo -

Kazutoshi Sugita,*, a Osamu Endo,b Shozo Asada,c Sumio Goto,d Hirofumi Yajima,e and Tadahiro Ishiie

aDia Analysis Service Inc., 8-5-1, Chuo, Ami-machi, Inashiki-gun, Ibaraki 300-0332, Japan, bNational Institute of Public Health, 4-6-1, Shirokanedai, Minato-ku, Tokyo 108-8638, Japan, cJapan Quality Assurance Organization, 1-8-12, Higashi-ohi, Shinagawa-ku, Tokyo 140-0011, Japan, dNational Institute of Environmental Studies, 16-2, Onogawa, Tsukuba-shi, Ibaraki 305-8506, Japan, and eScience University of Tokyo, Faculty of Science, 1-1, Kagurasaka, Shinjuku-ku, Tokyo 162-0825, Japan

Size-fractionated air-borne particles and gaseous samples were collected using Andersen low pressure impactor with polyurethane foam at Tokyo. Dioxin concentrations of these particles and gaseous substances were measured with high resolution gas chromatograph/high resolution mass spectrometer (HRGC/HRMS). Particle diameter distribution has two peaks, one around 0.7 mu m and the other around 5 mu m both in summer and winter. But, dioxin has a peak at around the particle diameter of 0.52 mu m. And, It was observed that smaller particle was the higher weight concentration of dioxins in the particle except in the case of Tetrachlorodibenzo-p-dioxins tetrachlorodibenzofurans (TeCDFs). From these results, it was recognized that 75% or more of toxic dioxin component was contained in particles of 1 mu m or smaller.